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71.
Gianluca Nasini Lucio Merlini Giovanni Dario Andreetti Gabriele Bocelli Paolo Sgarabotto 《Tetrahedron》1982,38(18):2787-2796
The absolute configuration of the asymmetric carbons and the axial chirality of the natural mold metabolite cercosporin (from .) have been established on the basis of X-ray analysis and chemical reactions. The results confirm the inherent dissymmetry of the perylenequinone ring, the twisting of which gives rise to the diastereoisomer isocercosporin. The energy barrier for the conversion of cercosporin into isocercosporin has been evaluated. 相似文献
72.
Riassunto In questo lavoro, si studia, per una classe di operatori quasi-lineari, il problema della dipendenza simultanea dai vincoli,
dai coefficienti dell'operatore e dai termini noti delle soluzioni di disequazioni variazionali ellittiche e delle soluzioni
forti di disequazioni variazionali paraboliche. L'esistenza di queste ultime è consequenza dei risultati precedenti.
Lavoro eseguito nell'ambito del G.N.A.F.A.—C.N.R. 相似文献
Summary We study the problem of the dependence from the data of the solutions of quasilinear elliptic variational inequalities. We also consider the case of the strong solutions of parabolic variational inequalities, whose existence has been proved as a consequence of the previous results.
Lavoro eseguito nell'ambito del G.N.A.F.A.—C.N.R. 相似文献
73.
We discuss the influence of a second neutral gauge boson to the Drell-Yan process. We find that for energies available in the near future and even at present energies, there are sizeable differences in the predictions of different models for the forward-backward asymmetry and the longitudinal polarization of the lepton. 相似文献
74.
Sum frequency generation surface vibrational spectroscopy and kinetic measurements using gas chromatography have been used to identify a reactive surface intermediate in situ during hydrogenation of benzene on a Pt(111) single crystal surface at Torr pressures. Upon adsorption at 310 K, both chemisorbed and physisorbed benzene coexist on the surface, a result which has not previously been observed. Kinetic measurements show a linear compensation effect for the production of both cyclohexane and cyclohexene. From these data the isokinetic temperature was identified and correlated to the chemisorbed benzene species, which were probed by means of vibrational spectroscopy. Additionally, chemisorbed benzene was determined to be a reactive intermediate, which is critical for hydrogenation. 相似文献
75.
In this paper we consider nonlinear boundary value problems whose simplest model is the following:
(0.1) 相似文献
76.
77.
Lucio Centrone 《代数通讯》2013,41(8):3491-3506
78.
Kemilly M. P. Pinheiro Roger C. Moreira Kariolanda C. A. Rezende Mrcio Talhavini Lucio P. L. Logrado Jos A. F. Baio Marcos R. V. Lanza Wendell K. T. Coltro 《Electrophoresis》2019,40(3):462-468
This study describes the development of an analytical methodology based on the use of microchip electrophoresis (ME) devices integrated with capacitively coupled contactless conductivity detection (C4D) for the separation and detection of inorganic anions in post‐blast explosive residues. The best separation condition was achieved using a running buffer composed of 35 mmol/L lactic acid, 10 mmol/L histidine and 0.070 mmol/L cetyl(trimethyl ammonium) bromide. For C4D measurements, the highest sensitivity was obtained applying a 700 kHz sinusoidal wave with excitation voltage of 20 Vpp. The separation of Cl?, NO3?, NO2?, SO42?, ClO4? and ClO3? was performed within ca. 150 s with baseline resolution and efficiencies between 4.4 × 104 and 1.7 × 105 plates/m. The found limits of detection ranged between 2.5 and 9.5 μmol/L. Last, real samples of post‐blast explosive residues were analyzed on the ME‐C4D devices obtaining successfully the determination of Cl?, NO3? and SO42?. The achieved concentration values varied between 12.8–72.5 mg/L for Cl?, 1.7–293.1 mg/L for NO3? and 1.3–201.3 mg/L for SO42?. The data obtained using ME‐C4D devices were in good agreement with the concentrations found by ion chromatography. The approach reported herein has provided short analysis time, instrumental simplicity, good analytical performance and low cost. Furthermore, the ME‐C4D devices emerge as a powerful and portable analytical platform for on‐site analysis demonstrating to be a promising tool for the crime scene investigation. 相似文献
79.
80.
Neutrino beams obtained from proton accelerators were first operated in 1962. Since then, neutrino beams have been intensively used in particle physics and evolved in many different ways. We describe the characteristics of various neutrino beams, relating them to the historical development of the physics studies and discoveries. We also discuss some of the ideas still under consideration for future neutrino beams.
相似文献